{"id":159284,"date":"2020-03-30T05:32:22","date_gmt":"2020-03-30T09:32:22","guid":{"rendered":"https:\/\/today.uconn.edu\/?p=159284"},"modified":"2020-03-27T14:28:00","modified_gmt":"2020-03-27T18:28:00","slug":"quantum-effect-triggers-unusual-material-expansion","status":"publish","type":"post","link":"https:\/\/today.uconn.edu\/2020\/03\/quantum-effect-triggers-unusual-material-expansion\/","title":{"rendered":"Quantum Effect Triggers Unusual Material Expansion"},"content":{"rendered":"

You know how you leave space in a water bottle before you pop it in the freezer\u2014to accommodate the fact that water expands as it freezes? Most metal parts in airplanes face the more common opposite problem. At high altitudes (and low temperatures) they shrink. To keep such shrinkage from causing major disasters, engineers make airplanes out of composites or alloys, mixing materials that have opposite expansion properties to balance one another out.<\/p>\n

New research conducted in part at UConn and the U.S. Department of Energy\u2019s Brookhaven National Laboratory may bring a whole new class of chemical elements into this materials science balancing act.<\/p>\n

As described in a paper just published on March 26 in Physical Review Letters<\/em><\/a>, scientists used x-rays at Brookhaven\u2019s National Synchrotron Light Source II<\/a> (NSLS-II)\u2014a U.S. Department of Energy Office of Science user facility\u2014and two other synchrotron research facilities to explore an unusual metal that expands<\/em> dramatically at low temperature. The experiments on samarium sulfide doped with some impurities revealed details about the material\u2019s atomic-level structure and the electron-based origins of its \u201cnegative thermal expansion.\u201d<\/p>\n

This work opens avenues for designing new materials where the degree of expansion can be precisely tuned by tweaking the chemical recipe. It also suggests a few related materials that could be explored for metal-mixing applications.<\/p>\n

\u201cIn practical applications, whether an airplane or an electronic device, you want to make alloys of materials with these opposite properties\u2014things that expand on one side and shrink on the other when they cool down, so in total it stays the same,\u201d explained Daniel Mazzone, the paper\u2019s lead author and a postdoctoral fellow at NSLS-II and Brookhaven Lab\u2019s Condensed Matter Physics and Materials Science Department.<\/p>\n

But materials that mimic water\u2019s expansion when chilled are few and far between. And while the expansion of freezing water is well understood, the dramatic expansion of samarium sulfide had never been explained.<\/p>\n

This samarium-based compound (specifically samarium sulfide with some yttrium atoms taking the place of a few samarium atoms) reveals competing electronic phases (somewhat analogous to the solid, liquid, and gaseous phases of water). Depending on external conditions such as temperature and pressure, electrons in the material can do different things. In some cases, the material is a gold-colored metal through which electrons can move freely\u2014a conductor. In other conditions, it\u2019s a black-colored semiconductor, allowing only some electrons to flow.<\/p>\n

The golden metallic state is the one that expands dramatically when chilled, making it an extremely unusual metal. Mazzone and his colleagues, including UConn physics professor Jason Hancock, an expert in materials with negative thermal expansion (that is, materials that expand when cold and shrink when warm), turned to x-rays and theoretical descriptions of the electrons\u2019 behavior to figure out why.<\/p>\n

At NSLS-II\u2019s Pair Distribution Function<\/a> (PDF) beamline, the scientists conducted diffraction experiments. They placed samples of their samarium metal in the beam of NSLS-II\u2019s x-rays and measured how the x-rays bounced off atoms making up the material\u2019s crystal structure.<\/p>\n

The team also used x-rays at the SOLEIL synchrotron in France and SPring-8 synchrotron in Japan to take a detailed look at what electrons were doing in the material at different stages of the temperature-induced transition.<\/p>\n

\u201cThese \u2018x-ray absorption spectroscopy\u2019 experiments can track whether electrons are moving into or out of the outermost \u2018shell\u2019 of electrons around the samarium atoms,\u201d explained co-corresponding author Ignace Jarrige, physicist at NSLS-II.<\/p>\n

If you think back to one of the basics of chemistry, you might remember that atoms with unfilled outer shells tend to be the most reactive. Samarium\u2019s outer shell is just under half full.<\/p>\n

The electron-tracking x-ray experiments revealed that electrons flowing through the samarium-sulfide metal were moving into that outer shell around each samarium atom. As each atom\u2019s electron cloud grew to accommodate the extra electrons, the entire material expanded.<\/p>\n

But the scientists still had to explain the behavior based on physics theories. With the help of Maxim Dzero, a professor at Kent State University, they were able to explain the effect with the so-called Kondo effect, named after physicist Jun\u00a0Kondo.<\/p>\n

The basic idea behind the Kondo effect is that electrons will interact with magnetic impurities in a material, aligning their own spins in the opposite direction of the larger magnetic particle to \u201cscreen out,\u201d or cancel, its magnetism.<\/p>\n

In the samarium-sulfide material, Dzero explained, the almost-half-full outer shell of each samarium atom acts as a tiny magnetic impurity pointing in a certain direction. \u201cAnd because you have a metal, you also find free electrons that can approach and cancel out these little magnetic moments,\u201d Dzero said.<\/p>\n

“This work connects negative thermal expansion to the Kondo effect, potentially guiding new materials discovery efforts in the context of moment screening in rare-earth systems,” said UConn’s Hancock.<\/p>\n

It\u2019s unusual for the Kondo effect to cause electrons to fill the outermost shell. More often, they go the other way\u2014leaving the shell\u2014which arises from a delicate energy balance dictated by basic quantum mechanical rules. These rules suggest that compounds incorporating two other elements in the same region of the periodic table\u2014the breakout section that contains the \u201ctransition elements\u201d\u2014might also attract extra electrons.<\/p>\n

\u201cIn most of these elements, because of the way the outer shell fills up following the rules of quantum mechanics, it is more energetically favorable for electrons to move out of the shell, but for a couple of these materials, the electrons can move in,\u201d Jarrige said. In addition to samarium (Sm), the other two are thulium (Tm) and ytterbium (Yb).<\/p>\n

It would be worth exploring compounds containing these other elements as additional possible ingredients for creating materials that expand upon cooling, Jarrige noted.<\/p>\n

Finally, the scientists noted that the extent of the negative thermal expansion in samarium sulfide can be tuned by varying the concentration of impurities.<\/p>\n

\u201cThis tunability makes this material very valuable for engineering expansion-balanced alloys,\u201d Mazzone said.<\/p>\n

\u201cThe application of highly developed many-body theory modeling was an important part of the work to identify the connection between the magnetic state of this material and its volume expansion,\u201d said Hancock. \u201cThis collaboration between Kent State, UConn, Brookhaven Lab, partner synchrotrons, and synthesis groups in Japan could potentially guide new materials discovery efforts that make use of the unusual properties of these rare-earth materials.\u201d<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

New research conducted in part at UConn may bring a whole new class of chemical elements into a delicate materials science balancing act.<\/p>\n","protected":false},"author":58,"featured_media":159429,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_crdt_document":"","wds_primary_category":0,"wds_primary_series":0,"wds_primary_attribution":0,"footnotes":""},"categories":[2226,2076,2225],"tags":[],"magazine-issues":[],"coauthors":[117],"class_list":["post-159284","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-clas","category-research","category-uconn-storrs"],"pp_statuses_selecting_workflow":false,"pp_workflow_action":"current","pp_status_selection":"publish","acf":[],"publishpress_future_action":{"enabled":false,"date":"2026-05-12 21:38:06","action":"change-status","newStatus":"draft","terms":[],"taxonomy":"category","extraData":[]},"publishpress_future_workflow_manual_trigger":{"enabledWorkflows":[]},"_links":{"self":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/159284","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/users\/58"}],"replies":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/comments?post=159284"}],"version-history":[{"count":5,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/159284\/revisions"}],"predecessor-version":[{"id":159430,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/159284\/revisions\/159430"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/media\/159429"}],"wp:attachment":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/media?parent=159284"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/categories?post=159284"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/tags?post=159284"},{"taxonomy":"magazine-issue","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/magazine-issues?post=159284"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/coauthors?post=159284"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}