{"id":161830,"date":"2020-06-17T11:01:11","date_gmt":"2020-06-17T15:01:11","guid":{"rendered":"https:\/\/today.uconn.edu\/?p=161830"},"modified":"2020-06-17T11:40:13","modified_gmt":"2020-06-17T15:40:13","slug":"uconn-army-research-lab-collaborate-new-portable-renewable-energy-technology","status":"publish","type":"post","link":"https:\/\/today.uconn.edu\/2020\/06\/uconn-army-research-lab-collaborate-new-portable-renewable-energy-technology\/","title":{"rendered":"UConn, Army Research Lab Collaborate on New Portable, Renewable Energy Technology"},"content":{"rendered":"<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">UConn\u2019s Associate Dean for Research and Industrial Partnerships, S. Pamir Alpay, and Yomery Espinal &#8217;18 PhD (ENG) have published a paper on a novel portable pyroelectric technology in <\/span><a href=\"https:\/\/www.cell.com\/cell-reports-physical-science\/fulltext\/S2666-3864(20)30070-9\">Cell Reports Physical Science<\/a> with support from the Army Research Laboratory. <\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Pyroelectric energy research is focused on how to generate energy from heat that would otherwise be wasted in a catalytic chemical reaction. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">When pyroelectric materials are heated, their polarization changes, leading to an electron flow that generates energy. These materials are commonly used in household devices like motion sensor lights, which detect body heat to determine when someone is near. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Anytime there is a catalytic reaction, heat is generated. These devices harness that heat and use it as energy. For example, a combustion engine in a car produces heat that, with this kind of technology, could be used to power the electrical functions of the car that otherwise rely on battery power. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">The Army Research Lab (ARL) is particularly interested in this technology because it can provide more power with less weight, which is important for soldiers carrying heavy bags. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">While scientists have been experimenting with pyroelectric power for decades, the technology proposed in this paper is completely novel. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">\u201cSomething like that doesn\u2019t exist,\u201d Alpay says. \u201cIt would give you the opportunity to recover some things that just go to waste.\u201d <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">The technology proposed in this publication is portable and has an extended lifetime. It uses on-chip combustion of methanol, a high-energy fuel, to harness energy from the reaction. The pyroelectric material converts waste heat from the reaction to usable power.<\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Vapor of a high-energy fuel, in this case methanol, is combusted on a thin, 440 nanometer film on platinized silicon wafers. The device converts the heat from this reaction into pyroelectric power. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Nanostructured iridium oxide is the top electrode and combustion catalyst. Iridium is a dense, corrosion and heat-resistant metal making it an excellent candidate for this application. Iridium oxide is first activated at temperatures as low as 105 degrees Celsius and fully catalyzes methanol to carbon dioxide at 120 degrees Celsius. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">This is an advantage compared to platinum-based catalysts, which do not achieve full conversion until 150 degrees Celsius. This means less heat must be applied to the device for it to be fully effective. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">This on-chip combustion technology has a 90% combustion efficiency rate. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">This technology would be significantly more powerful than lithium-ion batteries, the common rechargeable batteries used in electronics. The energy density of methanol is 22 times greater than a lithium-ion battery. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">While this study only provided researchers with a preliminary version of this technology, it can have far-reaching applications. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Pyroelectric power is a clean alternative to fossil fuels and nuclear energy, which still constitute more than 80% of the United States\u2019s power. Thus, this technology has broad energy applications on large and small scales. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Brendan Hanrahan, Ph.D., a staff materials engineer at ARL, led this effort on ARL\u2019s side of the partnership. Hanrahan operated as a critical hinge to bring the ARL and UConn researchers together for this project. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Espinal earned her Ph.D. at UConn and was awarded the Bridge to the Doctorate Fellowship in 2013, which supports members of underrepresented groups in STEM. She began working at the Army Research Lab with Hanrahan during her time in the program and spent two years there. Immediately after graduation, she was offered a position with the Defense Advanced Research Projects Agency (DARPA). <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">Over the past few years, UConn and ARL have fostered a productive partnership that will likely continue for years to come. <\/span><\/span><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">\u201cThe key to our successful collaboration is that we play off each other\u2019s strengths,\u201d says Dr. Hanrahan,. \u201cWithout one another [Alpay\u2019s] theories would remain theories and we&#8217;re just shooting in the dark. So that\u2019s why it\u2019s such a great partnership.\u201d <\/span><\/span><\/p>\n<p>&nbsp;<\/p>\n<p><em>Follow UConn Research on<\/em> <a href=\"https:\/\/nam10.safelinks.protection.outlook.com\/?url=https%3A%2F%2Ftwitter.com%2FUConnResearch&amp;data=02%7C01%7Ctom.breen%40uconn.edu%7C1e8627a6b92a43e5684908d7ed3625f7%7C17f1a87e2a254eaab9df9d439034b080%7C0%7C0%7C637238689125957999&amp;sdata=z0iyASkN%2F09jiDUCGuy6F81l5wlY60i%2BLgnhNgGjSdo%3D&amp;reserved=0\"><em>Twitter<\/em><\/a><em> &amp;<\/em> <a href=\"https:\/\/nam10.safelinks.protection.outlook.com\/?url=https%3A%2F%2Fwww.linkedin.com%2Fcompany%2Fuconnresearch&amp;data=02%7C01%7Ctom.breen%40uconn.edu%7C1e8627a6b92a43e5684908d7ed3625f7%7C17f1a87e2a254eaab9df9d439034b080%7C0%7C0%7C637238689125957999&amp;sdata=52JQT6oy1HSZW3uzRQZ83b1igFXgzmUg7I6BuEqf06E%3D&amp;reserved=0\"><em>LinkedIn<\/em><\/a><em>.<\/em><\/p>\n<p><span style=\"margin: 0px; line-height: 107%; font-family: 'Georgia',serif; font-size: 12pt;\"><span style=\"color: #000000;\">\u00a0<\/span><\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>New research from UConn and the US Army suggests a novel technology could have major implications for the generation of energy on small and large scales. <\/p>\n","protected":false},"author":68,"featured_media":161831,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_crdt_document":"","wds_primary_category":0,"wds_primary_series":0,"wds_primary_attribution":0,"footnotes":""},"categories":[1866,2076,2225],"tags":[],"magazine-issues":[],"coauthors":[1902],"class_list":["post-161830","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-engr","category-research","category-uconn-storrs"],"pp_statuses_selecting_workflow":false,"pp_workflow_action":"current","pp_status_selection":"publish","acf":[],"publishpress_future_action":{"enabled":false,"date":"2026-05-27 02:08:17","action":"change-status","newStatus":"draft","terms":[],"taxonomy":"category","extraData":[]},"publishpress_future_workflow_manual_trigger":{"enabledWorkflows":[]},"_links":{"self":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/161830","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/users\/68"}],"replies":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/comments?post=161830"}],"version-history":[{"count":4,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/161830\/revisions"}],"predecessor-version":[{"id":161948,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/161830\/revisions\/161948"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/media\/161831"}],"wp:attachment":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/media?parent=161830"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/categories?post=161830"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/tags?post=161830"},{"taxonomy":"magazine-issue","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/magazine-issues?post=161830"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/coauthors?post=161830"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}