{"id":22594,"date":"2016-08-10T17:31:01","date_gmt":"2016-08-10T17:31:01","guid":{"rendered":"http:\/\/d45h139.public.uconn.edu\/sites\/news\/?p=22594"},"modified":"2024-11-27T11:22:45","modified_gmt":"2024-11-27T16:22:45","slug":"novel-smart-materials-inspired-by-sea-creatures","status":"publish","type":"post","link":"https:\/\/today.uconn.edu\/2016\/08\/novel-smart-materials-inspired-by-sea-creatures\/","title":{"rendered":"Novel Smart Materials Inspired by Sea Creatures"},"content":{"rendered":"<figure id=\"attachment_22595\" aria-describedby=\"caption-attachment-22595\" style=\"width: 700px\" class=\"wp-caption aligncenter\"><img decoding=\"async\" class=\"wp-image-22595 img-responsive lazyload\" data-src=\"http:\/\/d45h139.public.uconn.edu\/sites\/news\/wp-content\/uploads\/sun160720b081-1024x682-1024x682.jpg\" alt=\"sun160720b081-1024x682\" width=\"700\" height=\"466\" src=\"data:image\/svg+xml;base64,PHN2ZyB3aWR0aD0iMSIgaGVpZ2h0PSIxIiB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciPjwvc3ZnPg==\" style=\"--smush-placeholder-width: 700px; --smush-placeholder-aspect-ratio: 700\/466;\" \/><figcaption id=\"caption-attachment-22595\" class=\"wp-caption-text\">UConn engineering Professor Luyi Sun, left, and graduate student Songshan Zeng, have created new &#8216;smart&#8217; materials that can change appearance and quickly revert to their original state, just like the squid and jellyfish that inspired them. (Sean Flynn\/UConn Photo)<\/figcaption><\/figure>\n<p><em>Combined Reports<\/em><br \/><em>This story originally appeared in <a href=\"https:\/\/today.uconn.edu\/2016\/08\/novel-smart-materials-inspired-sea-creatures\/?utm_source=launchdistribution&amp;utm_medium=email&amp;utm_campaign=daily_email#\/\">UConn Today<\/a><\/em><\/p>\n<p>A suite of new materials developed in the lab of UConn researcher Luyi Sun can change their appearance and quickly revert to their original state, just like the squid and jellyfish that inspired them.<\/p>\n<p>The research was published recently in <em><a href=\"http:\/\/www.nature.com\/ncomms\/2016\/160708\/ncomms11802\/full\/ncomms11802.html\">Nature<\/a>.<\/em><\/p>\n<p>The materials, which are stretchable, thin, and slightly squishy, have potential applications in smart windows, display optics, and encryption technology.<\/p>\n<p>\u201cThere are several marine animals that can very smartly and actively alter their skin\u2019s structure and color,\u201d says Sun, associate professor of chemical and biomolecular engineering who is affiliated with UConn\u2019s Institute of Materials Science. \u201cIn this work, we follow two examples, squid and jellyfish respectively, to create different mechanical responsive devices.\u201d<\/p>\n<p>In the first case, the jellyfish\u2019s skin is very flat and transparent most of the time, but by wrinkling its skin, it can cause a deformation that creates an opaque appearance.<\/p>\n<p>Songshan Zeng, a graduate student in Sun\u2019s lab and first author on the <em>Nature<\/em> article, says that change is likely a defensive mechanism.<\/p>\n<p>In the second example, the squid can instantaneously change its\u00a0skin color by contracting the tiny muscles that encircle its pigment cells. When the muscles contract, the pigment cells expand to expose more color. When the muscles relax, the pigment cells contract and the change is reversed.<\/p>\n<p>Sun\u2019s research group and collaborator Dianyun Zhang, assistant professor of mechanical engineering, decided to mimic these qualities, to see if they could develop materials that would achieve these same quick, reversible changes in appearance.<\/p>\n<p>They began with a thin, rigid film, and then attached a thicker layer of soft, stretchable elastomer. When the layers are joined and stretched, the rigid layer develops cracks and folds. As this layer is stretched, the cracks and folds grow in size in proportion to the force exerted. As a result, the surface becomes rough and scatters the light that passes through, thereby changing the material\u2019s transparency.<\/p>\n<p>Zeng describes the process, \u201cWhen we stretch it, we are able to change the transparency, the surface becomes rough and will scatter light that passes through, and the UConn logo underneath the sample disappears.\u201d<\/p>\n<p><iframe title=\"Amazing Material Reveals Text when Stretched\" width=\"500\" height=\"375\" src=\"https:\/\/www.youtube.com\/embed\/WtF4NEmZGTk?feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p>Three variants on the material were created based on similar principles. By altering the qualities of both the flexible and the rigid layers \u2013 by adding pigment, luminescent, or reflective materials \u2013 different outcomes were achieved.<\/p>\n<p>In one case, after dye was added to the elastomer layer, the material showed strong fluorescence as it was stretched. Stretching and releasing the material allowed open cracks to form or disappear, switching the fluorescence on or off. \u201cThe cracks are like opening and closing windows to control the penetration of UV light that is able to pass through,\u201d Sun explains. \u201cA larger open crack will allow more UV light through and allow the fluorescence of the dye underneath the film to be observed.\u201d Once the stretch force is no longer applied, the cracks will close and the fluorescence disappears.<\/p>\n<p><iframe title=\"Amazing Material Changes Opacity when Stretched\" width=\"500\" height=\"375\" src=\"https:\/\/www.youtube.com\/embed\/j8vD9d5eeEo?feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p>In another experiment, the material changed color. Dye was added to both the rigid thin film and the stretchy elastomer, one inlaid with green and the other with orange luminescent dyes as well as a reflective layer. Under UV light in the relaxed state, the sample showed green luminescence. When it was stretched, orange luminescence developed as the cracks occurred. \u201cThe color intensity is actually proportional to the size of the cracks or strain applied,\u201d says Zeng.<\/p>\n<p><iframe title=\"Amazing Material Reveals Logo when Stretched\" width=\"500\" height=\"375\" src=\"https:\/\/www.youtube.com\/embed\/IT8i9E37Xo8?feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p>In the next experiment, the researchers manipulated the reflective layer to reveal or conceal a pattern. On the reflective layer they applied highly reflective patterned titanium oxide along with elastomer\/carbon black. When relaxed, the material is not luminescent, but when it is stretched, a message is revealed as the fluorescence reaches the reflective coating.<\/p>\n<p><iframe title=\"Amazing Material Changes Color when Stretched\" width=\"500\" height=\"375\" src=\"https:\/\/www.youtube.com\/embed\/-mbLsTcfpf8?feature=oembed\" frameborder=\"0\" allow=\"accelerometer; autoplay; clipboard-write; encrypted-media; gyroscope; picture-in-picture; web-share\" referrerpolicy=\"strict-origin-when-cross-origin\" allowfullscreen><\/iframe><\/p>\n<p>After initial development, the material was put to the test to study its durability. To verify the integrity of the material, Zeng tested it through more than 50,000 stretch\/release cycles. The mechanical responsive optical properties were not lost, despite the extensive testing.<\/p>\n<p>\u201cThe robustness of the material was well demonstrated!\u201d says Sun.<\/p>\n<p>Sun says the researchers are working with partners to commercialize the material.<\/p>\n<p>Zeng says there are many applications for this type of material. One possibility is to use it for smart windows. \u201cTo get privacy for windows, all you would need to do is just stretch the material a little bit to obtain opacity,\u201d he says, adding that it could also be used as display optics for toys, or even in encryption technology.<\/p>\n<p>\u201cWe are very excited for all these applications,\u201d he adds.<\/p>\n<p>Sun is now experimenting with modifying the new material. \u201cThe current material needs UV light to activate it,\u201d he says, \u201cbut we are now modifying it to show color change under daylight.\u201d<\/p>\n<p>Sun\u2019s group also has more bio-inspired materials with different applications in the works, with results to be published later this summer.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>A suite of new materials developed in the lab of UConn researcher Luyi Sun can change their appearance and quickly revert to their original state, just like the squid and jellyfish that inspired them.<\/p>\n","protected":false},"author":122,"featured_media":221727,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_crdt_document":"","wds_primary_category":0,"wds_primary_series":0,"wds_primary_attribution":0,"footnotes":""},"categories":[1866],"tags":[],"magazine-issues":[],"coauthors":[43],"class_list":["post-22594","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-engr"],"pp_statuses_selecting_workflow":false,"pp_workflow_action":"current","pp_status_selection":"publish","acf":[],"publishpress_future_action":{"enabled":false,"date":"2026-05-20 04:29:59","action":"change-status","newStatus":"draft","terms":[],"taxonomy":"category","extraData":[]},"publishpress_future_workflow_manual_trigger":{"enabledWorkflows":[]},"_links":{"self":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/22594","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/users\/122"}],"replies":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/comments?post=22594"}],"version-history":[{"count":1,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/22594\/revisions"}],"predecessor-version":[{"id":221940,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/posts\/22594\/revisions\/221940"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/media\/221727"}],"wp:attachment":[{"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/media?parent=22594"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/categories?post=22594"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/tags?post=22594"},{"taxonomy":"magazine-issue","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/magazine-issues?post=22594"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/today.uconn.edu\/wp-rest\/wp\/v2\/coauthors?post=22594"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}